A novel approach for itaconic acid extraction: Mixture of trioctylamine and tridodecylamine in different diluents

Asci Y. S., Inci I.

JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, cilt.18, sa.5, ss.1705-1709, 2012 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 18 Sayı: 5
  • Basım Tarihi: 2012
  • Doi Numarası: 10.1016/j.jiec.2012.03.010
  • Dergi Adı: JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.1705-1709
  • Anahtar Kelimeler: Extraction, Itaconic acid, Amine mixture, AQUEOUS-SOLUTIONS, ASPERGILLUS-TERREUS, AMBERLITE LA-2, PICOLINIC-ACID, ACRYLIC-ACID, EQUILIBRIA, AMINE
  • İstanbul Üniversitesi Adresli: Evet

Özet

Extraction of itaconic acid has been investigated from aqueous solutions by six kind of different solutions of trioctylamine (TOA)-tridodecylamine (TDA) mixtures. Solvents have selected as dimethyl phthalate (DMP), methyl isobutyl ketone (MIBK), 2-octanone, 1-octanol, cyclohexyleacetate (CHA), and 1-decanol. Distribution and equilibrium data for design of separation equipments have been obtained as a result of batch extraction of itaconic acid. It has been calculated that distribution coefficients (D), loading factors (Z), extraction efficiency (E). The maximum removal of itaconic acid has been obtained as 98.39% with DMP and 3.14 mol L-1 initial concentration of TOA-TDA mixture. (C) 2012 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.