Cyclic voltammetric investigation of the 6-keto 9-17 mono methyl substitute of octadeconoic acids

Erturan, S; Yalcin, M; Tanyolac, S

Cyclic voltammetric investigation of the 6-keto 9-17 mono methyl substitute of octadeconoic acids

INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY, cilt.40, sa.1, ss.25-31, 2001 (SCI-Expanded)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 40 Sayı: 1
Basım Tarihi: 2001
Dergi Adı: INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Sayfa Sayıları: ss.25-31
İstanbul Üniversitesi Adresli: Hayır

Özet

In this study the 6-keto 9-17 mono methyl substituted octadeconoic acids have been investigated in nonaqueous media (acetonitrile) by cyclic voltammetry. Tetrabutylammonium tetrafluoraborate (TBAFB) is used as the supporting electrolyte (C16H36BF4N) The oxidation potentials are determined against Ag/AgBF4 (0.1M) reference electrode. Effects of keto and methyl substituent on the oxidation potentials have been investigated, and kinetics and the mechanisms of reaction established.