Influence of synthesis conditions on particle morphology of nanosized Cu/ZnO powder by polyol method


Altincekic T. G. , Boz I.

BULLETIN OF MATERIALS SCIENCE, cilt.31, ss.619-624, 2008 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 31 Konu: 4
  • Basım Tarihi: 2008
  • Doi Numarası: 10.1007/s12034-008-0098-x
  • Dergi Adı: BULLETIN OF MATERIALS SCIENCE
  • Sayfa Sayıları: ss.619-624

Özet

Cu/ZnO in nanosizes have been synthesized using ethylene glycol at various conditions. The effects of reaction temperature, extent of reduction, various precursors such as CuX2.nH(2)O,ZnX2.nH(2)O (X = Cl-, NO3-, CH3CO2-), the addition of water and the removal of volatile compounds including water were studied by X-ray diffraction (XRD), scanning electron microscopy (SEM), and dynamic light scattering (DLS). Cu/ZnO powders with an average diameter of as low as 50 nm was obtained with a very low polydispersity in the absence of a protective polymer. Ethylene glycol oxidation products were also identified by Fourier transform infrared (FTIR) spectroscopy. The morphology of Cu/ZnO powders and the yield of powders are found to be strongly dependent on the synthesis conditions.