Synthesis and characterization of polymeric Pd(II), Pt(IV), and Au(III) complexes of 2,2 '-(1,4-phenylenedivinylene)-bis-8-hydroxyquinoline

Tavman, Aydın; Hayvali, Mustafa; Filik, Hayati; Kilic, Emine

doi:10.1134/s0036023606080080

Synthesis and characterization of polymeric Pd(II), Pt(IV), and Au(III) complexes of 2,2 '-(1,4-phenylenedivinylene)-bis-8-hydroxyquinoline

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Tavman A., Hayvali M., Filik H., Kilic E.

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, vol.51, no.8, pp.1198-1201, 2006 (SCI-Expanded)

Publication Type: Article / Article
Volume: 51 Issue: 8
Publication Date: 2006
Doi Number: 10.1134/s0036023606080080
Journal Name: RUSSIAN JOURNAL OF INORGANIC CHEMISTRY
Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Page Numbers: pp.1198-1201
Istanbul University Affiliated: Yes

Abstract

The complexes of 2,2'-(1,4-Phenylenedivinylene)-bis-8-hydroxyquinoline (LH2) with K2PdCl4, H2PtCl6 and HAuCl4 were synthesized and characterized with H-1-and C-13- NMR, elemental analysis, FT-IR, and molar conductivity. Au(III) and Pt(IV) complexes have characteristic conductance, while the Pd(II) complex has a non-ionic structure according to the molar conductivity and elemental analysis.