In this study, as a novel design with the collaboration of a fluorene and sulfide-based copolymer for Li-ion battery application is presented. Polyfluorene-co-polydisulfide is prepared with desired functional groups to yield a conductivity and good adhesion. These critical and important features are performed by preparing polymers with proper functional groups. The preparation process is accomplished via Suzuki coupling process under Pd catalyst by combining separately synthesized 4,4 '-dibromodiphenyl disulfide in combination with 9,9-dioctylfluorene-2,7-bis(trimethylborate). The fully obtained capacity of the silicon particles, that is, at C/10 with the capacity of 1250 mAh g(-1) after the 500th cycle, approves the good performance by preserving capacity stability till 600th cycles. The designed and synthesized polymer binder with different functionalities and carbon nanotube additive show better characteristics such as conductivity, high polarity, and binding adhesion. (c) 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 136, 48303.