Synthesis of Novel Acrylic Modified Water Reducible Alkyd Resin: Investigation of Acrylic Copolymer Ratio Effect on Film Properties and Thermal Behaviors


Akgun N., Buyukyonga O. N. , Acar I. , Guclu G.

POLYMER ENGINEERING AND SCIENCE, cilt.56, ss.947-954, 2016 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 56 Konu: 8
  • Basım Tarihi: 2016
  • Doi Numarası: 10.1002/pen.24324
  • Dergi Adı: POLYMER ENGINEERING AND SCIENCE
  • Sayfa Sayıları: ss.947-954

Özet

New four-component water reducible acrylic modified alkyd resins that are based on 1,3-propanediol and contain different ratios of acrylic copolymer (AC) were synthesized by using a novel four-stage fatty acid method. The final content of solids in the water reducible acrylic modified alkyd resins was 60% by weight. After the modified alkyd resin films were cured at 150 degrees C for 1 h, it was observed that the use of AC as the modifier component had improved their physical and chemical surface coating properties and thermal behaviors. Experimental results show that the optimum AC ratio is 40% of the equivalent amount of AC to alkyd resin. Low-volatile organic compounds (VOC) content water reducible acrylic modified alkyd resins yielded soft and flexible films with high chemical/thermal resistance, suitable for manufacturing of surface coating binders. (C) 2016 Society of Plastics Engineers