The FT-IR spectra of pyrazinamide complexes of transition metal(II) tetracyanonickelate

Akyuz S.

JOURNAL OF MOLECULAR STRUCTURE, cilt.651, ss.541-545, 2003 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 651
  • Basım Tarihi: 2003
  • Doi Numarası: 10.1016/s0022-2860(02)00675-0
  • Dergi Adı: JOURNAL OF MOLECULAR STRUCTURE
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.541-545
  • İstanbul Üniversitesi Adresli: Hayır

Özet

M(PZA)(2)Ni(CN)(4) (where M = Mn, Co,Fe, Ni or Cd; PZA = pyrazinamide} complexes have been prepared for the first time and their FT-IR spectra are reported in the 400-4000 cm(-1) region. The spectral features suggest that the compounds are similar in structure to the Hofmann type two dimensional coordination polymer compounds, formed with Ni(CN)(4)(-2) ions bridged by M(PZA)(2)(+2) cations. PZA is coordinated to M(II) through the oxygen atom of the carbonyl group. (C) 2002 Elsevier Science B.V. All rights reserved.