Corrosion Inhibition of Mild Steel in Sulfuric Acid by a Newly Synthesized Schiff Base: An Electrochemical, DFT, and Monte Carlo Simulation Study
ELECTROANALYSIS, cilt.32, ss.3145-3158, 2020 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 32
- Basım Tarihi: 2020
- Doi Numarası: 10.1002/elan.202060461
- Dergi Adı: ELECTROANALYSIS
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Aerospace Database, Applied Science & Technology Source, BIOSIS, Chimica, Communication Abstracts, Metadex, Civil Engineering Abstracts
- Sayfa Sayıları: ss.3145-3158
- İstanbul Üniversitesi Adresli: Hayır
Özet
Effects of using a synthesized aminothiazole (BZ) Schiff base at different concentrations with and without the addition of 1 mM of KI on the corrosion mitigation of mild steel (MS) in 0.5 M sulphuric acid (H2SO4) solutions are studied electrochemically using direct and alternating currents (DC and AC) techniques. Besides, the adsorption and thermodynamic parameters are calculated in a temperature range of 293-323 K. Furthermore, Mott-Schottky analysis is used to study the type of oxide layer on the MS surface. Quantum chemical calculations and Monte Carlo simulation techniques are used, and both confirmed the experimental results.