1,2-Bis-(2-benzimidazolyl)-1,2-ethanediol and 1,4-bis-(2-benzimidazolyl)-1,2,3,4-butanetetraol PdCl2 complexes


Tavman A., Ulkuseven B., Agh-Atabay N.

TRANSITION METAL CHEMISTRY, cilt.25, sa.3, ss.324-328, 2000 (SCI İndekslerine Giren Dergi) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 25 Konu: 3
  • Basım Tarihi: 2000
  • Doi Numarası: 10.1023/a:1007082222512
  • Dergi Adı: TRANSITION METAL CHEMISTRY
  • Sayfa Sayıları: ss.324-328

Özet

The 1,2-bis-(2-benzimidazolyl)-1,2-ethanediol (EH2) and 1,4-bis-(2-benzimidazolyl)-1,2,3,4-butanetetraol (TH4) ligands form 4-coordinate mono- and bi-metallic complexes with PdCl2, respectively. In Pd(EH2)Cl-2 the ligand acts as a bidentate through two of the nitrogen atoms. On the other hand, in Pd-2(TH4)Cl-4 the ligand coordinates to two palladium atoms through both bis-benzimidazole nitrogen atoms and two oxygen atoms of the hydroxy groups, forming two different isomers. The complexes were characterised by analytical data, magnetic susceptibility, molar conductivity, and also by i.r., H-1- and C-13-n.m.r. spectra.