The effect of various cations and pH on the adsorption of U(VI) on Amberlite IR-118H resin

Kilislioglu A.

APPLIED RADIATION AND ISOTOPES, cilt.58, sa.6, ss.713-717, 2003 (SCI-Expanded) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 58 Sayı: 6
  • Basım Tarihi: 2003
  • Doi Numarası: 10.1016/s0969-8043(03)00116-7
  • Dergi Adı: APPLIED RADIATION AND ISOTOPES
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.713-717
  • İstanbul Üniversitesi Adresli: Hayır

Özet

The effects of various metal cations and pH on the adsorption of uranium(VI) on strongly acidic cation exchanger Amberlite IR-118H (AIR-118H) were studied. The metal cations suppress U(VI) adsorption differently depending on their ionic radii. Adsorption of U(VI) on AIR-118H peaks at pH 3.4, which was attributed to the occurrence of different forms of U(VI) at different pH values. The adsorption data were then processed using the Frumkin-Fowler-Guggenheim equation, and the standard free energy of adsorption was calculated. (C) 2003 Elsevier Science Ltd. All rights reserved.

Abstract: The effects of various metal cations and pH on the adsorption of uranium(VI) on strongly acidic cation exchanger Amberlite IR-118H (AIR-118H) were studied. The metal cations suppress U(VI) adsorption differently depending on their ionic radii. Adsorption of U(VI) on AIR-118H peaks at pH 3.4, which was attributed to the occurrence of different forms of U(VI) at different pH values. The adsorption data were then processed using the Frumkin-Fowler-Guggenheim equation, and the standard free energy of adsorption was calculated.