N,S-, S-, S,S-, 2-substituted dienes from halo-1,3-butadienes

Ibis, C; Gokmen, Z

doi:10.1080/10426500500272194

N,S-, S-, S,S-, 2-substituted dienes from halo-1,3-butadienes

Atıf İçin Kopyala

Ibis C., Gokmen Z.

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, cilt.181, sa.4, ss.939-945, 2006 (SCI-Expanded)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 181 Sayı: 4
Basım Tarihi: 2006
Doi Numarası: 10.1080/10426500500272194
Dergi Adı: PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Sayfa Sayıları: ss.939-945
İstanbul Üniversitesi Adresli: Hayır

Özet

Mono(thio) substituted dienes 1 gave 3a-g, 5, and 7 with piperazine derivatives in dichloromethane. Hexachlorobutadiene 14 in a water-ethanol mixture in the presence of sodium hydroxide reacted with thiol 15 to give the mono(thio) substituted thioether 16 and di(thio) substituted thioether 17. 18 was obtained from the reaction of 16 with m-CPBA in chloroform. 9 was obtained from the reaction of l,2,3,4,4-pentachloro-(1-2-hydroxyethylthio)-1,3- butadiene 8 with 47% HI, and 11 was synthesized from the reaction of 8 with concentrated H2SO4 and KBr. Compounds 9 and 11 gave in the reaction with m-CPBA in chloroform 10, 12, and 13, respectively.