A New Diterpenoid Alkaloid from the Roots of a White-Flowering Aconitum orientale Sample


Mericli A. H., Cagal-Yurdusever N., ÖZÇELİK H., Zapp J., Kiemer A. K.

HELVETICA CHIMICA ACTA, cilt.95, sa.2, ss.314-319, 2012 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 95 Sayı: 2
  • Basım Tarihi: 2012
  • Doi Numarası: 10.1002/hlca.201100139
  • Dergi Adı: HELVETICA CHIMICA ACTA
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.314-319
  • İstanbul Üniversitesi Adresli: Evet

Özet

From the roots of a white-flowering Aconitum orientale Miller sample, collected in Artvin-Savsat, Turkey, a new diterpenoid alkaloid named aconitorientaline (1) was isolated, along with the known diterpenoid alkaloids septentiriodine, lappaconitine, finaconitine, ranaconitine, puberanidine and delstaphinine (Fig.). The structure of 1 was established on the basis of 1H- and 13C-NMR, DEPT, 1H,1H-COSY, NOESY, HSQC, and HMBC studies. All the known compounds were identified by comparison of their 1H- and 13C-NMR data and co-TLC behavior with those of authentic samples.