CRYSTAL STRUCTURE OF 2-(3,5-DIMETHOXYPHENYLAMINO)-3-CHLORONAPHTHALENE-1,4-DIONE

Bayrak N., Yildiz M., Yildirim H., Sahin M., Tuyun A. F.

BULLETIN OF THE CHEMICAL SOCIETY OF ETHIOPIA, cilt.32, sa.3, ss.603-608, 2018 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 32 Sayı: 3
  • Basım Tarihi: 2018
  • Doi Numarası: 10.4314/bcse.v32i3.18
  • Dergi Adı: BULLETIN OF THE CHEMICAL SOCIETY OF ETHIOPIA
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.603-608
  • Anahtar Kelimeler: Naphthoquinones, Aminochloronaphthoquinone, X-Ray diffraction, NAPHTHOQUINONE DERIVATIVES, FACILE SYNTHESIS, DYES
  • İstanbul Üniversitesi Adresli: Evet

Özet

2-(3,5-Dimethoxyphenylamino)-3-chloronaphthalene-1,4-dione compound was prepared from the nucleophilic substitution reaction of 2,3-dichloro-1,4-naphthoquinone with 3,5-dimethoxyphenylamine at reflux temperature according to literature reported previously. Single-crystal X-ray diffraction analysis was carried out to confirm the structure of the title compound. The title compound, C18H14ClNO4, crystallizes in the triclinic space group P-1, a = 7.0016(6) angstrom, b = 7.7937(6) angstrom, c = 15.6218(11) angstrom, beta = 97.238(4)degrees, V = 782.44(11) angstrom(3), Z = 2, R-1= 0.0525, wR(2) = 0.1329.