Reactivity study of 2,4-dinitrobuta-1,3-dienes towards mono-, poly-, and persulfanyl conjugated dienes by regiospecific vinyl group activation

Ibis C., TUYUN A. F.

Phosphorus, Sulfur and Silicon and the Related Elements, vol.187, no.10, pp.1161-1172, 2012 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 187 Issue: 10
  • Publication Date: 2012
  • Doi Number: 10.1080/10426507.2012.670337
  • Journal Name: Phosphorus, Sulfur and Silicon and the Related Elements
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.1161-1172
  • Keywords: Nitro compounds, dinitrodienes, sulfides, polyhalogenated compounds, polysulfanylbuta-1,3-dienes, persulfanylalkenes, nitroalkenes, click chemistry, POLYHALOGENATED NITROBUTADIENES, NUCLEOPHILIC-SUBSTITUTION, SUBSEQUENT REACTIONS, CHEMISTRY, DERIVATIVES, BUTADIENES, AMINES, 2-NITROPENTACHLORO-1,3-BUTADIENE, NITRODIENES, THIOLS
  • Istanbul University Affiliated: No

Abstract

Polyhalogenated nitrobuta-1,3-dienes are unique reagents in organic synthesis and have been employed in several well-known and recently developed areas of application. This study describes the scope and application of 1,1,3,4-tetrachloro-2,4-dinitrobuta-1,3-diene in organic synthesis as well as methods for the preparation of poly-and perfunctionalized 2,4-dinitrobuta-1,3- dienes, and characterization of all obtained compounds. © Taylor and Francis Group, LLC.