2-hydroxy-1-naphthaldehyde S-(alkyl)-N-4-phenylthiosemicarbazone complexes with Fe(III), Co(III), Ni(II), and Cu(II) ions

Kizilcikli, İrfan; Mesut, Y

doi:10.1081/sim-120021929

2-hydroxy-1-naphthaldehyde S-(alkyl)-N-4-phenylthiosemicarbazone complexes with Fe(III), Co(III), Ni(II), and Cu(II) ions

Atıf İçin Kopyala

Kizilcikli I., Mesut Y.

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, cilt.33, sa.6, ss.949-963, 2003 (SCI-Expanded)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 33 Sayı: 6
Basım Tarihi: 2003
Doi Numarası: 10.1081/sim-120021929
Dergi Adı: SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Sayfa Sayıları: ss.949-963
İstanbul Üniversitesi Adresli: Hayır

Özet

2-Hydroxy-l-naphthaldehyde S-(alkyl)-N-4-phenyl-thiosemicarbazones (alkyl = CH3, C2H5, n-C3H7 and C6H5CH2) were synthesized according to common procedures. The 1: 1 and 1:2 metal to ligand complexes with Fe(III), Co(III), Ni(II), and Cu(II) salts were synthesized and characterized by analytical data, IR, H-1 NMR spectroscopy, magnetic susceptibility, molar conductivity and TGA analysis. It was determined that the tridentate behavior of the ligands is accomplished via the phenolic hydroxy group, the azomethine and thioamide nitrogens.