Liquid-liquid equilibria of (limonene plus linalool plus ethylene glycol or diethylene glycol or triethylene glycol or 1,2-propylene glycol) ternary systems

Sevgili L. M., Sahin S., Kirbaslar S. I.

JOURNAL OF CHEMICAL AND ENGINEERING DATA, cilt.53, sa.3, ss.737-741, 2008 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 53 Sayı: 3
  • Basım Tarihi: 2008
  • Doi Numarası: 10.1021/je700577t
  • Dergi Adı: JOURNAL OF CHEMICAL AND ENGINEERING DATA
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.737-741
  • İstanbul Üniversitesi Adresli: Evet

Özet

Liquid-liquid equilibrium (LLE) data of the solubility (binodal) curves and tie-line compositions were examined for mixtures of (limonene (1) + linalool (2) + ethylene glycol or diethylene glycol or triethylene glycol or 1,2-propylene glycol (3)) at 298.15 K and 101.3 +/- 0.7 kPa. The relative mutual solubility of linalool is higher in the limonene layers than in the ethylene glycol or diethylene glycol or triethylene glycol or 1,2-propylene glycol layers. The reliability of the experimental tie-line data was confirmed by using the Othmer-Tobias correlation. The LLE data of the ternary systems was predicted by the UNIFAC method. Distribution coefficients and separation factors were evaluated for the immiscibility region.