The novel macrocyclic and linear-chain thioethers from perchlorobutadiene and dithioles


Ibis C., Yilmaz N.

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, cilt.179, sa.12, ss.2543-2548, 2004 (SCI-Expanded) identifier identifier

Özet

Compounds 3a-c, 4a,b, 5a-c, and 6a,c were obtained front the reactions of perchlorobutadiene (1) with 1,4-butanedithiol (2a), 1,5pentanethiol (2b), and 2.2'-(ethietze-dioxyl)diethanethiol (2c) in ethanol in the presence of sodium hydroxide. Compounds 7a,b were obtained from, the reactions of thioethers 3a,b with m-chlorperbenzoic acid in CHCl3.