The synthesis and characterization of novel quinone-amine polymers from the reactions of 2,3-dichloro-1,4-naphthoquinone and polyoxypropylenediamines
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, vol.191, no.3, pp.438-443, 2016 (SCI-Expanded, Scopus)
- Publication Type: Article / Article
- Volume: 191 Issue: 3
- Publication Date: 2016
- Doi Number: 10.1080/10426507.2015.1100187
- Journal Name: PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
- Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Page Numbers: pp.438-443
- Istanbul University Affiliated: Yes
Abstract
A series of novel N- and N,N'-bis(quinonyl)amines were synthesized from the reactions of 2,3-dichloro-1,4-naphthoquinone (1) and polyoxypropylenediamines. The novel quinone-amine polymers were treated with some thiols in next step and N,S- substituted compounds were obtained. The structures of the novel products were characterized by micro-analysis, H-1 NMR, UV-VIS, C-13 NMR, and MS. The electrochemical properties of some of the novel amine-quinone polymers derivatives were also investigated by cyclic voltammetry. The number of molecular weight (Mn) of polymer compounds was also determined by Gel Permeation Chromatography (GPC).