Synthesis and properties of starch-graft-acrylic acid/Na-montmorillonite superabsorbent nanocomposite hydrogels

Al E., Guclu G., Iyim T. B., Emik S., Ozgumus S. K.

JOURNAL OF APPLIED POLYMER SCIENCE, vol.109, no.1, pp.16-22, 2008 (SCI-Expanded, Scopus)

  • Publication Type: Article / Article
  • Volume: 109 Issue: 1
  • Publication Date: 2008
  • Doi Number: 10.1002/app.27968
  • Journal Name: JOURNAL OF APPLIED POLYMER SCIENCE
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.16-22
  • Istanbul University Affiliated: Yes

Abstract

The graft copolymerization of acrylic acid (AA) onto starch was carried out with monomer/starch weight ratio = 1.5. Cerium ammonium nitrate (CAN) and N,N′-methylenebis acrylamide (NMBA) were used as initiator and crosslink agent, respectively. Na-montmorillonite was used as nanoparticles. Starch-graft-acrylic acid/Na-MMT (S-g-AA/MMT) nanocomposite hydrogels were characterized by X-ray diffraction (XRD) and FTIR analysis. The effect of Na-MMT content in nanocomposite hydrogels on the swelling behavior was investigated. Increasing the Na-MMT/monomers ratio up to 1% causes an increment in water absorbency, which indicates that Na-MMT can improve the ability of water absorbency but further increase of Na-MMT causes a decrease in water absorbency. In addition, we describe the removal of safranine T from aqueous solutions using S-g-AA/MMT nanocomposite hydrogels. Effects of various parameters such as treatment time, initial dye concentration, and amount of the Na-MMT were investigated. The Freundlich equations were used to fit the equilibrium isotherms.

The graft copolymerization of acrylic acid (AA) onto starch was carried out with monomer/starch weight ratio = 1.5. Cerium ammonium nitrate (CAN) and N,N'-methylenebis acrylamide (NMBA) were used as initiator and crosslink agent, respectively. Na-montmorillonite was used as nanoparticles. Starch-graft-acrylic acid/Na-MMT (S-g-AA/MMT) nanocomposite hydrogels were characterized by X-ray diffraction (XRD) and FTIR analysis. The effect of Na-MMT content in nanocomposite hydrogels on the swelling behavior was investigated. Increasing the Na-MMT/monomers ratio up to 1% causes an increment in water absorbency, which indicates that Na-MMT can improve the ability of water absorbency but further increase of Na-MMT causes a decrease in water absorbency. In addition, we describe the removal of safranine T from aqueous solutions using S-g-AA/MMT nanocomposite hydrogels. Effects of various parameters such as treatment time, initial dye concentration, and amount of the Na-MMT were investigated. The Freundlich equations were used to fit the equilibrium isotherms. (C) 2008 Wiley Periodicals, Inc.