The novel N,S-substituted halonitrodienes from the reactions of thiosubstituted nitrodiene with piperazine and morpholine


Ibis C. , Onul N.

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, vol.180, no.12, pp.2787-2792, 2005 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 180 Issue: 12
  • Publication Date: 2005
  • Doi Number: 10.1080/104265090968163
  • Title of Journal : PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
  • Page Numbers: pp.2787-2792

Abstract

The substituted 1,2-dibromomethanethio nitrodiene 2 was obtained from the addition of bromine to S-substituted nitrodien 1 in carbon tetrachloride. N,S-substituted compounds 4a-h were synthesized from the reactions of compound 2 with several substituted piperazine derivatives 3a-h in dichloromethane. N,S-substituted compounds 6 and 8 were synthesized from the reaction of 2 with morpholine (5) and thiomorpholine (7) in dichloromethane, respectively. Dibutadienyl piperazines 10, 12, and 14 were synthesized from the reactions of 2 with homopiperazine (9), piperazine (11), and 2,5-dimethylpiperazine (13), respectively.