Thermal, mechanical, and morphological characterization studies of poly(2,6-dimethyl-1,4-phenylene oxide) blends with polystyrene and brominated polystyrene


Aroguz A., Baysal B.

JOURNAL OF APPLIED POLYMER SCIENCE, cilt.75, ss.225-231, 2000 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 75 Konu: 2
  • Basım Tarihi: 2000
  • Dergi Adı: JOURNAL OF APPLIED POLYMER SCIENCE
  • Sayfa Sayıları: ss.225-231

Özet

The miscibility of the binary and ternary blends of poly(2,6-dimethyl-1,4-phenylene oxide), brominated polystyrene, and polystyrene was investigated using a differential scanning calorimeter. The morphology of these blends was characterized by scanning electron microscopy. These studies revealed a close relation between the blend structure and its mechanical properties. The compatibilizing effect of poly(2,6-dimethyl-1,4-phenylene oxide) on the miscibility of the polystyrene/brominated polystyrene blends was examined. It was found that poly(2,6-dimethyl-1,4-phenylene oxide), which was miscible with polystyrene and partially miscible with brominated polystyrene, compatibilizes these two immiscible polymers if its contention exceeds 33 wt 9b. Upon the addition of poly(2,6-dimethyl-1,4-phenylene oxide) to the immiscible blends of polystyrene/brominated polystyrene, we observed a change in the morphology of the mixtures. An improvement in the mechanical properties was noticed. (C) 2000 John Wiley & Sons, Inc.