Removal of Basic Dyes from Aqueous Solutions by Crosslinked-Acrylic Acid/Acrylamidopropane Sulfonic Acid Hydrogels


Akkaya M. C. , Emik S., Guclu G. , Iyim T. B. , Ozgumus S. K.

JOURNAL OF APPLIED POLYMER SCIENCE, cilt.114, sa.2, ss.1150-1159, 2009 (SCI İndekslerine Giren Dergi) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 114 Konu: 2
  • Basım Tarihi: 2009
  • Doi Numarası: 10.1002/app.30704
  • Dergi Adı: JOURNAL OF APPLIED POLYMER SCIENCE
  • Sayfa Sayıları: ss.1150-1159

Özet

In this study, Acrylic acid (AA)/2-acrylamido-2-methlypropane sulfonic acid (AMPS) hydrogels were prepared by free radical polymerization in aqueous solutions of AA, AMPS, and N,N-methylenebisacrylamide (NMBA) as crosslinker. Potassium persulfate (PPS)/potassium bisulfide (PBS) were used as initiator and accelerator pair. The water absorption capacities and dye adsorption properties of the hydrogels were investigated. Adsorption properties of the hydrogels, were evaluated by depending on different adsorption conditions such as different initial dye concentration and contact time. The concentrations of the dyes were determined using UV/Vis Spectrophotometer at wavelength 530 nm for safranine T (ST) and 622 nm for brilliant cresyl blue (BCB). Adsorption kinetic studies showed that pseudo-first order kinetic model is suitable to explain the adsorption kinetic data of the hydrogels. Langmuir and Freundlich isotherm models were used to describe adsorption data. The result revealed that the adsorption of basic dyes onto hydrogels fit very well both Langmuir and Freundlich isotherms. (C) 2009 Wiley Periodicals, Inc. J Appl Polym Sci 114: 1150-1159, 2009

In this study, Acrylic acid (AA)/2-acrylamido-2-methlypropane sulfonic acid (AMPS) hydrogels were prepared by free radical polymerization in aqueous solutions of AA, AMPS, and N,N-methylenebisacrylamide (NMBA) as crosslinker. Potassium persulfate (PPS)/potassium bisulfide (PBS) were used as initiator and accelerator pair. The water absorption capacities and dye adsorption properties of the hydrogels were investigated. Adsorption properties of the hydrogels were evaluated by depending on different adsorption conditions such as different initial dye concentration and contact time. The concentrations of the dyes were determined using UV/Vis Spectrophotometer at wavelength 530 nm for safranine T (ST) and 622 nm for brilliant cresyl blue (BCB). Adsorption kinetic studies showed that pseudo-first order kinetic model is suitable to explain the adsorption kinetic data of the hydrogels. Langmuir and Freundlich isotherm models were used to describe adsorption data. The result revealed that the adsorption of basic dyes onto hydrogels fit very well both Langmuir and Freundlich isotherms.