Modeling vapor pressures of solvent systems with and without a salt effect: An extension of the LSER approach

Senol A.

JOURNAL OF CHEMICAL THERMODYNAMICS, cilt.81, ss.1-15, 2015 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 81
  • Basım Tarihi: 2015
  • Doi Numarası: 10.1016/j.jct.2014.09.002
  • Dergi Adı: JOURNAL OF CHEMICAL THERMODYNAMICS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.1-15
  • İstanbul Üniversitesi Adresli: Evet

Özet

A new polynomial vapor pressure approach for pure solvents is presented. The model is incorporated into the LSER (linear solvation energy relation) based solvation model framework and checked for consistency in reproducing experimental vapor pressures of salt- containing solvent systems. The developed two structural forms of the generalized solvation model (Senol, 2013) provide a relatively accurate description of the salting effect on vapor pressure of (solvent + salt) systems. The equilibrium data spanning vapor pressures of eighteen (solvent + salt) and three (solvent (1) + solvent (2) + salt) systems have been subjected to establish the basis for the model reliability analysis using a log- ratio objective function.