Crystal Structures of 2-Chloro-3-((3-(trifluoromethyl)phenyl)amino)naphthalene-1,4-dione and 2-Chloro-3-((4-(trifluoromethyl)phenyl)amino)naphthalene-1,4-dione

Yildirim H., Yildiz M., Bayrak N., Sahin M., Tuyun A. F.

CRYSTALLOGRAPHY REPORTS, cilt.64, sa.7, ss.1030-1033, 2019 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 64 Sayı: 7
  • Basım Tarihi: 2019
  • Doi Numarası: 10.1134/s1063774519070289
  • Dergi Adı: CRYSTALLOGRAPHY REPORTS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.1030-1033
  • İstanbul Üniversitesi Adresli: Evet

Özet

2-Chloro-3-((3-(trifluoromethyl)phenyl)amino)naphthalene-1,4-dione (1) and 2-chloro-3-((4-(trifluoromethyl)phenyl)amino)naphthalene-1,4-dione (2) were obtained according to the method reported previously. The crystal structures of both compounds were determined by the single crystal X-ray diffraction method. The molecules are non-planar: torsion angles around the N-C(naphthoquinone) bond are 32.62 degrees and 30.61 degrees for 1 and 2, respectively. In both crystals, hydrogen bonds N-H center dot center dot center dot O and N-H center dot center dot center dot Cl exist.