SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF N-(2-{[(2E)-2-(2-HYDROXYBENZYLIDENE)HYDRAZINYLI CARBONYL}-PHENYL)BENZAMIDE (HL) AND ITS Co(II), Fe(III), Cu(II) AND Zn(II) COMPLEXES. X-RAY CRYSTAL STRUCTURE OF HL


Khan R., Tavman A. , Gurbuz D. , Arfan M., Cinarli A.

BULLETIN OF THE CHEMICAL SOCIETY OF ETHIOPIA, cilt.32, ss.111-124, 2018 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 32 Konu: 1
  • Basım Tarihi: 2018
  • Doi Numarası: 10.4314/bcse.v32i1.10
  • Dergi Adı: BULLETIN OF THE CHEMICAL SOCIETY OF ETHIOPIA
  • Sayfa Sayıları: ss.111-124

Özet

N-(2-1{[(2E)-2-(2-hydroxybenzylidene)hydrazinyl]carbonyl}phenyli)benzamide (HL) and its Co(II), Fe(III), Cu(II) and Zn(II) perchlorate complexes were synthesized. The structures of HL and its complexes were confirmed on the basis of elemental analysis and FT-IR, FT-Raman, H-1-NMR spectra. TGA, magnetic moment and molar conductivity measurements were carried out for the complexes. In addition, the crystal structure of HL was determined by X-ray diffraction at room temperature. It crystallizes in the monoclinic, space group C2/c and Z=4. HL has an interesting structure due to the presence of two intramolecular hydrogen bonds. It behaves as a bidentate ligand through the C=N nitrogen and OH oxygen atoms in its chelate complexes that they have 1:2 M:L (metal:ligand) ratio. The Fe(III), Cu(II) and Zn(II) complexes, [Fe(HL)(L)(H2O)(2)](ClO4)(2), [Cu(HL)(2)](ClO4)(2 center dot)3H(2)O, [Zn(HL)(2)](ClO4)(2)center dot H2O are 2:1 electrolytes whereas the Co(II) complex, [Co(HL)(L)(H2O)]ClO4 center dot H2O, is 1:1 electrolyte according to the molar conductivity data.