Novel N,S- and S,S-substituted dienes synthesized from mercapto triazole and some amine derivatives

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Ibis C., Aydinli G.

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, vol.182, no.7, pp.1427-1436, 2007 (SCI-Expanded)

• Publication Type: Article / Article
• Volume: 182 Issue: 7
• Publication Date: 2007
• Doi Number: 10.1080/10426500701196499
• Journal Name: PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
• Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
• Page Numbers: pp.1427-1436
• Istanbul University Affiliated: Yes

Abstract

2-Nitrodiene 1 reacted with 3-mercapto-1,2,4-triazole and cyclohexyl thiol to yield compounds 3 and4, respectively. Compounds 7a-d were obtained by reactions of 6a-d with 2. The novel N,S-substituted dienes 9a-c were obtained by treatment of compound 6b with the piperazine derivatives 8a-c. Compound 6b was reacted with 10 to give compound 11 as a new morpholine derivative. Compound 6b gave a new monobutadienyl homopiperazine 13 when reacted with homopiperazine in methylene chloride. Compound 4 was structurally characterized by single-crystal X-ray diffraction.