Trace nickel determination in seawater matrix using combination of dispersive liquid-liquid microextraction and triethylamine-assisted Mg(OH)<sub>2</sub> method

Kublay İ. Z., KOÇOĞLU E. S., Oflu S., ARVAS B., YOLAÇAN Ç., BAKIRDERE S.

ENVIRONMENTAL MONITORING AND ASSESSMENT, cilt.195, sa.7, 2023 (SCI-Expanded) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 195 Sayı: 7
  • Basım Tarihi: 2023
  • Doi Numarası: 10.1007/s10661-023-11435-y
  • Dergi Adı: ENVIRONMENTAL MONITORING AND ASSESSMENT
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, ABI/INFORM, Agricultural & Environmental Science Database, Aqualine, Aquatic Science & Fisheries Abstracts (ASFA), BIOSIS, CAB Abstracts, Compendex, EMBASE, Environment Index, Food Science & Technology Abstracts, Geobase, Greenfile, Pollution Abstracts, Public Affairs Index, Veterinary Science Database, Civil Engineering Abstracts
  • İstanbul Üniversitesi Adresli: Hayır

Özet

In order to eliminate the effects of seawater matrix on the precise/accurate determination of elements, new and efficient analytical procedure requires. In this study, co-precipitation method based on the triethylamine (TEA)-assisted Mg(OH)(2) was performed to eliminate side-effects of seawater medium on the determination with flame atomic absorption spectrometry (FAAS) prior to the preconcentration of nickel by an optimized dispersive liquid-liquid microextraction (DLLME) method. Under the optimum conditions of the presented method, the limit of detection and quantification (LOD, LOQ) values obtained for nickel were found as 16.1 and 53.8 & mu;g kg(-1), respectively. Seawater samples collected from West Antarctic region were used for real sample applications to check the accuracy and applicability of developed method, and satisfying recovery results (86-97%) were obtained. In addition to this, the digital image-based colorimetric detection system and the UV-Vis system were applied to confirm the applicability of the developed DLLME-FAAS method in other analytical systems.