Tetradecanol dehydrogenation over CuO catalyst supported on BaO, CaO and MgO
REACTION KINETICS AND CATALYSIS LETTERS, cilt.83, sa.1, ss.137-146, 2004 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 83 Sayı: 1
- Basım Tarihi: 2004
- Doi Numarası: 10.1023/b:reac.0000037387.96533.1e
- Dergi Adı: REACTION KINETICS AND CATALYSIS LETTERS
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.137-146
- İstanbul Üniversitesi Adresli: Evet
Özet
Bimetallic Cu/Mg, Ca, Ba mixed oxide compounds acted as catalyst in the dehydrogenation of tetradecanol into tetradecanal, and were characterized by thermal gravimetric analysis, surface area, X-ray diffraction, temperature-programmed reduction and desorption of CO2. Alkaline earth oxides increased the total basic site concentration in the order of Mg>Ca>Ba. A correlation was found between the total basic site concentration and initial dehydrogenation rate.