Tetradecanol dehydrogenation over CuO catalyst supported on BaO, CaO and MgO


Boz I. , Pozan G., Gurkaynak M. A.

REACTION KINETICS AND CATALYSIS LETTERS, cilt.83, ss.137-146, 2004 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 83 Konu: 1
  • Basım Tarihi: 2004
  • Doi Numarası: 10.1023/b:reac.0000037387.96533.1e
  • Dergi Adı: REACTION KINETICS AND CATALYSIS LETTERS
  • Sayfa Sayıları: ss.137-146

Özet

Bimetallic Cu/Mg, Ca, Ba mixed oxide compounds acted as catalyst in the dehydrogenation of tetradecanol into tetradecanal, and were characterized by thermal gravimetric analysis, surface area, X-ray diffraction, temperature-programmed reduction and desorption of CO2. Alkaline earth oxides increased the total basic site concentration in the order of Mg>Ca>Ba. A correlation was found between the total basic site concentration and initial dehydrogenation rate.