Synthesis of some new S-, SS- and N,S-substituted 1,3-halonitrodienes


Ibis C., Brimo W., Aydinli G.

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, cilt.170, ss.221-231, 2001 (SCI İndekslerine Giren Dergi) identifier

  • Cilt numarası: 170
  • Basım Tarihi: 2001
  • Dergi Adı: PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
  • Sayfa Sayıları: ss.221-231

Özet

Mono(thio) substituted butadiene compounds 3a-c are prepared by mixing 2-nitropentachlorobutadiene (1) with thiols (2a-c). 2-Nitrodiene 1 gives bis(thio)substituted 4a and 4d by the reaction with the same thiols in EtOH containing sodium hydroxide. N,S-Substituted 1,3-butadienes 6a-h were obtained by the reactions of 3a-c with primary amines. S-Substituted nitrodiene compounds 3a-c give 8a-c and 10a-c by the reaction with piperazines 7 and 9 in ether.