Synthesis, spectroscopic and crystallographic characterization of the cobalt(III) ternary mixed-ligand complexes of N(4)-allyl/methyl thiosemicarbazones, N,N,N',N'-tetramethylethylenediamine and azide

Bal-Demirci T., AKKURT M., Yalcin S. P., Buyukgungor O.

TRANSITION METAL CHEMISTRY, cilt.35, sa.1, ss.95-102, 2010 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 35 Sayı: 1
  • Basım Tarihi: 2010
  • Doi Numarası: 10.1007/s11243-009-9300-2
  • Dergi Adı: TRANSITION METAL CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.95-102
  • İstanbul Üniversitesi Adresli: Hayır

Özet

Mixed-ligand ternary cobalt(III) complexes consisting of N,N,N',N'-tetramethylethylenediamine (tmen), R-salicylaldehyde-N(4)-allyl/methyl thiosemicarbazones (R=3-OMe (L-I/L-II) or H (L-III/L-IV) and azide, of general formula [CoL(tmen)(N-3)], were synthesized and characterized by physico-chemical and spectroscopic methods. The crystal structure of [CoLI(tmen)(N-3)] has a slightly distorted octahedral coordination geometry involving the O, N and S atoms of thiosemicarbazone.