Reactions of 2,3-dichloro-1,4-naphthoquinone with piperidine, amine and some thiol nucleophile

Patan A., Goksel F. S., ŞAHİNLER AYLA S.

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, cilt.196, sa.7, ss.647-655, 2021 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 196 Sayı: 7
  • Basım Tarihi: 2021
  • Doi Numarası: 10.1080/10426507.2021.1901700
  • Dergi Adı: PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Chemical Abstracts Core
  • Sayfa Sayıları: ss.647-655
  • Anahtar Kelimeler: 2,3-Dichloro-1,4-naphthoquinone, 3-piperidine methanol, thiols, UV–Vis spectroscopy
  • İstanbul Üniversitesi Adresli: Evet

Özet

The reactions of 2,3-dichloro-1,4-naphthoquinone (DCNQ) with 3-piperidine methanol and piperonyl amine were carried out and N-substituted quinone derivatives were obtained. Then N-substituted derivatives were treated with some thio nucleophile to synthesize N,S-substituted compounds. The structures of all compounds were characterized by spectroscopic methods (FT-IR, H-1 NMR, C-13 NMR, Mass spectroscopy) and microanalysis. The absorption behaviors of novel compounds were investigated with UV-Vis spectroscopy in different solutions such as ethanol and chloroform.