The reactions of some alkyl(thio)-substituted 2-nitrodienes with piperazines and a structural study


Ibis C. , Sayil C., Ozkok F.

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, vol.61, no.9, pp.1174-1179, 2006 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 61 Issue: 9
  • Publication Date: 2006
  • Doi Number: 10.1515/znb-2006-0921
  • Title of Journal : ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES
  • Page Numbers: pp.1174-1179

Abstract

Thiosubstituted nitrodiene compound la was obtained from 2-nitropentachlorobutadiene and dodecanethiol. Compound 1b was prepared from 2-nitropentachlorobutadiene and hexadecanethiol. Monosubstituted diene compounds la and 1b reacted with piperazines such as derivatives of 2 and 4 in CH2Cl2 and gave the novel compounds. 2-Nitro-3,4,4-trichloro-1-dodecylthio-1-(2-fluorophenylpiperazinyl]-1,3-butadiene (3d) was synthesized and its crystal structure was determined.