The FT-IR spectra of transition metal 3-aminopyridine tetracyanonickelate complexes

Akyuz S.

JOURNAL OF MOLECULAR STRUCTURE, cilt.449, sa.1, ss.23-27, 1998 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 449 Sayı: 1
  • Basım Tarihi: 1998
  • Doi Numarası: 10.1016/s0022-2860(98)00328-7
  • Dergi Adı: JOURNAL OF MOLECULAR STRUCTURE
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.23-27
  • İstanbul Üniversitesi Adresli: Hayır

Özet

FT-IR spectra of M(3apy)(2)Ni(CN)(4) {where M = Mn, Fe, Co, Ni, Cu, Zn or Cd; 3apy = 3-aminopyridine} complexes are reported for the first time in the 400-4000 cm(-1) range. The spectral features suggest that the compounds are similar in structure to the Hofmann-type complexes with infinite polymeric layers formed with Ni(CN)(4)(2-) ions bridged by M(3apy)(2)(2+) cations. It is concluded that the ring nitrogen and not the amino nitrogen is involved in complex formation. (C) 1998 Elsevier Science B.V. All rights reserved.