The synthesis of new S- and N,S-substituted halo nitro dienes by the reactions of 1-bromo-1,2,4,4-tetrachloro-3-nitrobuta-1,3-diene with thiols and cyclic amines

Ibis C., TUYUN A. F., Aydinli G.

Phosphorus, Sulfur and Silicon and the Related Elements, cilt.185, sa.10, ss.2014-2023, 2010 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 185 Sayı: 10
  • Basım Tarihi: 2010
  • Doi Numarası: 10.1080/10426500903453318
  • Dergi Adı: Phosphorus, Sulfur and Silicon and the Related Elements
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.2014-2023
  • Anahtar Kelimeler: Halides, nitro compounds, nucleophilic substitutions, piperazine derivatives, thiols, NITROBUTADIENES, THIOETHERS, CHEMISTRY, DITHIOLS, AGENTS
  • İstanbul Üniversitesi Adresli: Evet

Özet

The substituted products alkyl(aryl)thio-tetrahalo-3-nitrobuta-1,3-dienes 3a-b were obtained from the reactions of 1-bromo-1,2,4,4-tetrachloro-3- nitrobuta-1,3-diene (1) with thiols. Further reactions of the substituted product alkyl(aryl)thio-tetrahalo-3-nitrobuta-1,3-dienes 3a-b in dichloromethane reacted with piperazine derivatives and morpholine to generate 5a-b and 7a-l. The structures of the new compounds were determined by microanalysis and spectroscopic data. Copyright © Taylor & Francis Group, LLC.