Dioxomolybdenum(VI) Complexes of 2-hydroxybenzaldehyde 4-phenyl-S-methylthiosemicarbazone(1)

Kurt Y. D., Pozan G. S., Kizilcikli I., Uelkueseven B.

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, cilt.33, sa.11, ss.844-849, 2007 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 33 Sayı: 11
  • Basım Tarihi: 2007
  • Doi Numarası: 10.1134/s1070328407110097
  • Dergi Adı: RUSSIAN JOURNAL OF COORDINATION CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.844-849
  • İstanbul Üniversitesi Adresli: Evet

Özet

Mixed ligand complexes of dioxomolybdenum(VI) with 2-hydroxybenzaldehyde 4-phenyl-S-methylthiosemicarbazone (H2L) were prepared with the formula [MoO2(L)D] (D = H,O, methyl, n-butyl, and n-undecyl alcohol, DMF, DMSO, pyridine, 4-picoline, and 3,5-lutidine). The compounds were characterized by elemental analysis, IR and H-1 NMR spectroscopy. The thermal decomposition of the compounds were investigated by using TGA, DTG, and DTA methods in air, and the thermal behavior depending on the second ligand molecule was discussed. A single crystal of the DMF coordinated complex was studied by X-ray diffractometry.