Thermal decomposition of N-1,N-4-diarylidene-S-methylthiosemicarbazone dioxouranium(VI) templates
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, vol.49, no.11, pp.1685-1688, 2004 (SCI-Expanded, Scopus)
- Publication Type: Article / Article
- Volume: 49 Issue: 11
- Publication Date: 2004
- Journal Name: RUSSIAN JOURNAL OF INORGANIC CHEMISTRY
- Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Page Numbers: pp.1685-1688
- Istanbul University Affiliated: Yes
Abstract
The solvated dioxouranium(VI) complexes [UO2(L)S] (S = H2O, methyl, ethyl-, iso-amyl-, n-octyl- and n-undecyl-alcohol) were prepared from salicyl- and 5-bromosalicylaldehyde S-methylthiosemicarbazones. The templates were characterized by elemental analysis, IR and UV-Vis spectroscopy, magnetic susceptibility, and molar conductivity. The thermal stability of the compounds was investigated in air depending on the solvent molecule.