Spectral characterization and crystal structure of 2-amino-N '-[(1Z)-1-(4-chlorophenyl)ethylidene]-benzohydrazide


ARFAN M., KHAN R., Tavman A. , SABA S.

JOURNAL OF SAUDI CHEMICAL SOCIETY, cilt.20, ss.40-44, 2016 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 20 Konu: 1
  • Basım Tarihi: 2016
  • Doi Numarası: 10.1016/j.jscs.2012.08.006
  • Dergi Adı: JOURNAL OF SAUDI CHEMICAL SOCIETY
  • Sayfa Sayıları: ss.40-44

Özet

The crystal structure of 2-amino-N'-[(1Z)-1-(4-chlorophenyl)ethylideneJbenzohydrazide (I) is determined by X-ray diffraction at room temperature. The structure of I also was characterized by elemental analysis, mass, FT-IR and NMR spectroscopic techniques. The compound crystallizes in triclinic system, and space group is P (1) over bar. Unit-cell dimensions are the following: a = 7.05380(10) angstrom, b = 7.65490(10) angstrom, c = 13.7094(4) angstrom, V = 694.01(2) angstrom(3), Z = 2. The title compound is nearly planar and has intermolecular N H center dot center dot center dot O hydrogen bonding. According to the spectral data, I exhibits an amide-iminol tautomerism. (C) 2012 King Saud University. Production and hosting by Elsevier B.V. All rights reserved.