An analytical investigation of complexes of 4-amino-3-thioxo-1,2,4-triazin-5(4h)-one and its 2- and S-methyl derivatives with Ni(II), Cu(II), and Zn(II)-chloride

Tanyolac S., Yalcin M., Ulkuseven B.

REVIEWS IN INORGANIC CHEMISTRY, vol.17, no.4, pp.333-344, 1997 (SCI-Expanded) identifier

  • Publication Type: Article / Review
  • Volume: 17 Issue: 4
  • Publication Date: 1997
  • Journal Name: REVIEWS IN INORGANIC CHEMISTRY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.333-344
  • Istanbul University Affiliated: No

Abstract

The ligands 4-amino-3-thioxo-1,2,4-triazin-5(4H)-one and its 2- and S-methyl derivatives have been synthesized and characterized. These ligands were reacted with Zn(II), Cu(II) and Ni(II)-chloride salts and their analytical dissociation constants were determined in dioxane/water (1/1,v/v) mixtures. Some of these coordination complexes were isolated at two different pH values. The coordination complexes synthesized at pH greater than or equal to 13.0 value show 5-one <----> 5-ol tautomerism. The metallated products have been characterized by using analytical data and IR spectroscopy.