New N,S-substituted diene compounds from reactions of mono(arylthio)-substituted polyhalo-2-nitrodienes with amines

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Atıf İçin Kopyala

Ibis C., Yilmaz N.

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, cilt.159, ss.87-98, 2000 (SCI-Expanded)

• Yayın Türü: Makale / Tam Makale
• Cilt numarası: 159
• Basım Tarihi: 2000
• Doi Numarası: 10.1080/10426500008043653
• Dergi Adı: PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
• Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier
• Sayfa Sayıları: ss.87-98
• İstanbul Üniversitesi Adresli: Hayır

Özet

S-mono to S,S-tetrasubstituted 1,3-nitrodiene compounds 3-6 have been obtained from the reaction of 2-nitropentahalobutadiene with p-methylthiophenol. Mono(thio)substituted diene compound 3 gives dibutadienyl piperazine 10 with piperazine in diethylether, and compounds 12a and 12b with piperazine derivatives. From 3, compounds 14a-h, with primary amines, and compounds 8a-c with secondary amines, are achieved. 16 was obtained from the reaction of compound 3 with p-phenylene diamine in CH2Cl2.