Trifluoromethylthiolation of Unsymmetrical lambda(3)-Iodane Derivatives: Additive-Free, Selective and Scalable Introduction of the SCF3 Group


NIKOLAIENKO P., Yildiz T. , RUEPING M.

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, cilt.2016, ss.1091-1094, 2016 (SCI İndekslerine Giren Dergi) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 2016 Konu: 6
  • Basım Tarihi: 2016
  • Doi Numarası: 10.1002/ejoc.201501623
  • Dergi Adı: EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
  • Sayfa Sayıları: ss.1091-1094

Özet

The reaction of copper trifluoromethyl sulfide with diaryliodonium salts provides a straightforward pathway for the synthesis of aryl trifluoromethyl thioethers under mild reaction conditions and within short reaction times. High chemoselectivity was achieved by using mesityl as a leaving group. A large range of novel [(het)aryl](mesityl)iodonium salts underwent this reaction under the optimized conditions to give the desired products in moderate to good yields.