Adsorption of acetic acid onto activated carbons produced from hazelnut shell, orange peel, and melon seeds

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HASDEMİR İ. M., YILMAZOĞLU E., Gungor S., HASDEMİR B.

APPLIED WATER SCIENCE, cilt.12, sa.12, 2022 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 12 Sayı: 12
  • Basım Tarihi: 2022
  • Doi Numarası: 10.1007/s13201-022-01797-y
  • Dergi Adı: APPLIED WATER SCIENCE
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, IBZ Online, CAB Abstracts, Compendex, Environment Index, Food Science & Technology Abstracts, Geobase, INSPEC, Veterinary Science Database, Directory of Open Access Journals
  • Anahtar Kelimeler: Agricultural waste, Activated carbon, Adsorption, Chemical activation, CHEMICAL ACTIVATION, WASTE, CONVERSION, REMOVAL
  • İstanbul Üniversitesi Adresli: Hayır

Özet

In this study, hazelnut shells, orange peel, and melon seeds were selected as raw materials in the preparation of activated carbon. Various activators at different concentrations under two activation temperatures of 300 degrees C and 500 degrees C were utilized. All produced adsorbents and a commercial activated carbon as a reference were used for the adsorption of acetic acid from its aqueous solutions in the various initial concentrations. The effect of the amounts of adsorbents was also studied. Removal efficiencies (R-e%) and adsorption capacities (Q(e)) were experimentally determined. Langmuir, Freundlich, and Temkin isotherms were modelled, and their parameters were calculated. The surface area, pore volumes, and average pore width of the activated carbons were characterized by N-2 adsorption at 77.35 K using the BET, t-plot, and BJH methods, respectively. The highest BET surface area of the activated carbon from hazelnut shells was obtained as 717.738 m(2)/g at 500 degrees C activation temperature and 60% H3PO4 concentration. SEM images and FTIR analyses were investigated. It was found that activated carbons of hazelnut shells and orange peel showed higher efficiencies than commercial activated carbon.