Liquid plus liquid equilibria of the (water plus tartaric acid plus Alamine 336 plus organic solvents) at 298.15 K


Uslu H.

FLUID PHASE EQUILIBRIA, vol.253, no.1, pp.12-18, 2007 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 253 Issue: 1
  • Publication Date: 2007
  • Doi Number: 10.1016/j.fluid.2006.12.019
  • Title of Journal : FLUID PHASE EQUILIBRIA
  • Page Numbers: pp.12-18

Abstract

The extraction of tartaric acid with Alamine 336 which is a mixture of tertiary amines (C-8-C-10) dissolved in five single solvents (cyclohexane, hexane, toluene, methyl isobutyl ketone, butan-1-ol) and three binary solvent mixtures (MIBK + toluene (50%, v/v), MIBK + hexane (50%, v/v), hexane + toluene (50%, v/v)) were investigated. All measurements were carried out at 298.15 K The extent to which the organic phase may be loaded with tartaric acid is expressed as a loading ratio, Z, extraction efficiency E and overall particular distribution coefficients D were calculated. Equilibrium complexation constants for (acid:amine) (1: 1), (1:2) and (2:3) have been determined. The maximum removal of tartaric acid is mass 97.983% with methyl isobutyl ketone with a 1.736 mol dm(-3) initial concentration of Alamine 336. (c) 2007 Elsevier B.V. All rights reserved.