The ONN-complexes of dioxomolybdenum(VI) with dibasic 2-hydroxy-1-naphthaldehyde S-methyl/allyl-4-phenyl-thiosemicarbazones


Kizilcikli I. , Eglence S. , Gelir A., Ülküseven B.

TRANSITION METAL CHEMISTRY, cilt.33, ss.775-779, 2008 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 33
  • Basım Tarihi: 2008
  • Doi Numarası: 10.1007/s11243-008-9110-y
  • Dergi Adı: TRANSITION METAL CHEMISTRY
  • Sayfa Sayıları: ss.775-779

Özet

New dioxomolybdenum(VI) complexes were prepared by reacting S-methyl/allyl-4-phenyl-thiosemicarbazones of 2-hydroxy-1-naphthaldehyde (L H-1(2) and L H-2(2)) and [MoO2(acac)(2)] in methyl, ethyl and propylalcohols. In the complexes the doubly deprotonated ligands are coordinated to molybdenum as tridentate ONN-donors through phenolic-oxygen, azomethine- and thioamide-nitrogen. The solid complexes of general formula [MoO2L(ROH)] which contain an alcohol (ROH) as second ligand were characterized by physico-chemical and spectroscopic methods. The fluorescence emission intensities of the compounds were recorded in chloroform, and the intensity changes were evaluated depending on chelation and time. The structure of the S-allyl-4-phenyl-thiosemicarbazone complex has been determined by the single crystal X-ray diffraction method.