Quaternary liquid-liquid equilibrium of water plus acetic acid plus propionic acid plus solvent (amyl alcohol, cyclohexyl acetate, or toluene) systems

Cehreli S., Bilgin M.

JOURNAL OF CHEMICAL AND ENGINEERING DATA, cilt.49, sa.5, ss.1456-1459, 2004 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 49 Sayı: 5
  • Basım Tarihi: 2004
  • Doi Numarası: 10.1021/je049848j
  • Dergi Adı: JOURNAL OF CHEMICAL AND ENGINEERING DATA
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.1456-1459
  • İstanbul Üniversitesi Adresli: Evet

Özet

Liquid-liquid equilibrium data of water + acetic acid + propionic acid + solvent (amyl alcohol, cyclohexyl acetate, and toluene) quaternary systems were determined. Solubility curves and tie lines were measured at 298.15 K. A comparison of the extracting capabilities of the solvents was made with respect to distribution coefficients, separation factors, and solvent-free selectivity bases. The reliability of the data was ascertained from Othmer-Tobias plots. We conclude that all solvents are suitable separating agents for dilute aqueous acetic and propionic acid mixtures.