Hydrogen plasma treated iron vanadate nanoparticles for efficient ammonia sensing


Kavraz P., Bhardwaj A., Fischer T., Kuritka I., Dmonte D. J., Mathur S., ...Daha Fazla

Applied Surface Science, cilt.722, 2026 (SCI-Expanded, Scopus) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 722
  • Basım Tarihi: 2026
  • Doi Numarası: 10.1016/j.apsusc.2025.165537
  • Dergi Adı: Applied Surface Science
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Chemical Abstracts Core, Chimica, Compendex, INSPEC
  • Anahtar Kelimeler: Ammonia sensor, Gas sensing, Hydrogen plasma, Iron vanadate, Nanoparticles
  • İstanbul Üniversitesi Adresli: Evet

Özet

In this study, we investigate the impact of hydrogen plasma treatment on the gas-sensing properties of iron vanadate (FeVO4) nanostructures. The FeVO4 nanoparticles were synthesized via a sol–gel method, followed by surface modification using hydrogen plasma. Both hydrogen plasma-treated (hp-FeVO4) and untreated (FeVO4) samples were systematically characterized using X-ray diffraction (XRD), scanning electron microscopy (SEM), and X-ray photoelectron spectroscopy (XPS) techniques. Gas sensing experiments revealed that hp-FeVO4 nanostructures exhibited a response to 50 ppm NH3 that was twice as high as that of untreated FeVO4 samples, highlighting the significant enhancement achieved through plasma surface engineering. Notably, the hp-FeVO4 sensor exhibited a response time of 72 s and a recovery time of 292 s, operating at a reduced temperature of 380 °C, possibly due to increased band bending on the plasma-treated surface. Moreover, the sensor exhibited promising repeatability, selectivity, and long-term stability without the need to incorporate noble metals. These findings highlight the strong potential of hydrogen plasma-modified iron vanadate for advanced gas sensing applications.