S-, S,S-, S,S,S- and N,S-substituted diene compounds and dibutadienylpiperazine compounds of 2-nitropentachlorobutadiene


Ibis C., Bozkurt N.

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, vol.177, no.3, pp.695-701, 2002 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 177 Issue: 3
  • Publication Date: 2002
  • Doi Number: 10.1080/10426500210270
  • Title of Journal : PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
  • Page Numbers: pp.695-701

Abstract

Nitrodiene compound 1 was stirred with allylthiol for a long time and compound 3 was obtained. Compound 1 gave bis(thio)substituted 2-nitrodiene compound 4 and tris(thio)substituted 2-nitrodiene compound 5 with 2 moles allylthiol in the presence of NaOH in ethanol. Mono(allylthio)substituted diene compound 3 gave dibutadienyl substituted piperazine compounds with piperazine 6 in CH2Cl2 (or diethylether). Compound 3 gave compound 9 with compound 8. Compounds 11a-e have been obtained from the reaction of compound 3 with compounds 10 a-e.