Synthetic exploitation of halogenated alkenes containing EWG: benzotriazole-mediated synthesis of benzoazetines and thermal transformations

Tuyun A. F.

RSC ADVANCES, cilt.4, sa.38, ss.19640-19645, 2014 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 4 Sayı: 38
  • Basım Tarihi: 2014
  • Doi Numarası: 10.1039/c4ra01425a
  • Dergi Adı: RSC ADVANCES
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.19640-19645
  • İstanbul Üniversitesi Adresli: Hayır

Özet

The series of stable benzoazetine derivatives (5a-d) based on nitrovinyl moieties have been synthesized via transamination of bisbenzotriazolyl derivatives (2a-c). Four new heptatomic aromatic cycloheterocumulenes (azacyclohepta-1,2,4,6-tetraene) occurring at the stage of the film-forming process by TVE have been obtained by rearrangement of benzoazetines. The highly strained products were characterized by IR spectroscopy.