Determination of triazines and N-methylcarbamate pesticides in water by high-performance liquid chromatography-diode array detection
INTERNATIONAL JOURNAL OF ENVIRONMENTAL ANALYTICAL CHEMISTRY, cilt.83, sa.9, ss.787-795, 2003 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 83 Sayı: 9
- Basım Tarihi: 2003
- Doi Numarası: 10.1080/0306731031000104731
- Dergi Adı: INTERNATIONAL JOURNAL OF ENVIRONMENTAL ANALYTICAL CHEMISTRY
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.787-795
- Anahtar Kelimeler: high-performance liquid chromatography, diode-array detection, water analysis, pesticides, N-methylcarbamates, triazines, SOLID-PHASE EXTRACTION, IONIZATION MASS-SPECTROMETRY, NITROGEN-PHOSPHORUS DETECTION, ONLINE TRACE-ENRICHMENT, LARGE-VOLUME INJECTION, POLAR PESTICIDES, DEGRADATION PRODUCTS, GAS-CHROMATOGRAPHY, DRINKING-WATER, SURFACE-WATER
- İstanbul Üniversitesi Adresli: Evet
Özet
A rapid and selective method for the simultaneous determination of triazine herbicides (atrazine, its degradation product desethylatrazine, simazine, prometryn, terbutryn) and N -methylcarbamate insecticides (propoxur, carbaryl and methiocarb) in surface water has been developed. A 0.5 L of the water sample was preconcentrated by passage through a 1 g C-18 solid-phase extraction cartridge. The retained compounds were eluted with 5 mL of methanol from the cartridge. The pesticides were separated and quantified by reversed-phase high-performance liquid chromatography with UV diode-array detection. Analytical separation was performed using a concave gradient elution with acetonitrile and water on a C-18 column. Prometryn and terbutryn were determined at 240 nm; propoxur, methiocarb at 204 nm and the others at 220 nm. Recoveries varied from 85 to 102% over concentrations at 0.025 and 0.2 mug L-1. The limits of detection for the compounds investigated are in the range of 0.005-0.012 mug L-1.