SYNTHESIS AND CHARACTERIZATION OF S,S-, S,S,S-, AND THIOMORPHOLINYL-SUBSTITUTED NITRODIENE COMPOUNDS AND A STRUCTURAL STUDY

Gokmen, Zeliha; Deniz, Nahide

doi:10.1080/10426507.2015.1024789

SYNTHESIS AND CHARACTERIZATION OF S,S-, S,S,S-, AND THIOMORPHOLINYL-SUBSTITUTED NITRODIENE COMPOUNDS AND A STRUCTURAL STUDY

Atıf İçin Kopyala

Gokmen Z., Deniz N. G.

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, cilt.190, sa.8, ss.1309-1319, 2015 (SCI-Expanded)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 190 Sayı: 8
Basım Tarihi: 2015
Doi Numarası: 10.1080/10426507.2015.1024789
Dergi Adı: PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Sayfa Sayıları: ss.1309-1319
İstanbul Üniversitesi Adresli: Evet

Özet

S,S- and S,S,S-substituted nitrodienes 3a, 3b, and 4a were synthesized by reactions of 1,1,2,4,4-pentachloro-3-nitro-1,3-butadiene with some thiols 4-chlorobenzylmercaptan and 2-chlorobenzylmercaptan in ethanol in the presence of sodium hydroxide. Thiomorpholine ring substituted nitrodienes 6c and 6d and were obtained from the reactions of the mono(thio)substituted nitrodienes with thiomorpholine in dichloromethane. The single crystal X-ray structure of 4-(1-thiomorpholinyl)-4-(butylsulfanyl)-1,1,2-trichloro-3-nitro-1,3-butadiene (6c) is reported. In this present paper, the structures of new compounds were characterized by using nuclear magnetic resonance (NMR) spectroscopy, mass spectrometry (MS), and Fourier transform infrared (FTIR) spectroscopy spectroscopic data.