Investigation of photocatalytic degradation of methyl orange using zinc oxide-supported chitosan hydrogel beads


KABA İ., Bozkurt R. N., KILIÇ B.

CHEMICAL ENGINEERING COMMUNICATIONS, vol.213, no.3, pp.466-483, 2026 (SCI-Expanded, Scopus) identifier identifier

  • Publication Type: Article / Article
  • Volume: 213 Issue: 3
  • Publication Date: 2026
  • Doi Number: 10.1080/00986445.2025.2556134
  • Journal Name: CHEMICAL ENGINEERING COMMUNICATIONS
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Chemical Abstracts Core, Chimica, Compendex, INSPEC
  • Page Numbers: pp.466-483
  • Istanbul University Affiliated: No

Abstract

In this study, chitosan-based ZnO supported hydrogels (CZ-H) were synthesized to evaluate their photocatalytic degradation performance against methyl orange (MO) dye. The composite hydrogels were characterized using X-ray Diffraction (XRD), UV-Vis DRS, Scanning Electron Microscopy (SEM-EDS), Thermogravimetric Analysis (TGA), and Fourier Transform Infrared Spectroscopy (FTIR). These characterization results confirmed the successful formation of the CZ-H composite structure. The band gap of the composite was approximately 2.77 eV, supporting enhanced photocatalytic activity. Photocatalytic experiments showed that CZ-H removed 74% of MO within 60 min, compared to 42% for pure chitosan beads, with reaction rate constants of 0.0237 min-1 and 0.0113 min-1, respectively. Moreover, the CZ-H beads demonstrated good reusability with minimal loss in efficiency over multiple cycles. These findings highlight the potential of CZ-H as a stable, effective, and reusable photocatalyst for the efficient removal of dyes from wastewater.